;selhch ;selective ge-1D long-range CH transfer ;using proton shaped pulse ;Selective 1D HCH experiment: a fast NMR tool that connect protons belonging to different spin systems ;Magnetic Resonance in Chemistry, 2011 ;DOI: 10.1002/mrc.2744 ;AVANCE version #include #include #include "d4=1s/(cnst2*4)" "d6=1s/(cnst3*4)" "d11=30m" "d13=4u" "d20=d13+p16+d16" "d21=d4-p16-d16-50u" 1 ze 2 d11 d1 d12 pl1:f1 pl2:f2 50u UNBLKGRAD p16:gp6 d16 3 p1 ph1 d21 50u p16:gp1 d16 pl0:f2 pl0:f1 (center (p12:sp12 ph1):f1 (p14:sp3 ph1):f2 ) 50u p16:gp2 d16 d21 pl2:f2 pl1:f1 (center (p1 ph4) (p3 ph3):f2 ) d21 50u p16:gp3 d16 pl0:f2 pl0:f1 d6 (center (p12:sp12 ph1):f1 (p24:sp7 ph1):f2 ) 50u pl2:f2 pl1:f1 p16:gp4 d16 d21 (p2 ph1) d6 (center (p1 ph1):f1 (p3 ph5):f2 ) d20 (p2 ph1):f1 d13 p16:gp5 d16 4u BLKGRAD go=2 ph31 d11 mc #0 to 2 F0(zd) exit ph1=0 ph2=0 ph3=0 2 ph4=1 ph5=0 ph6=2 ph31=0 2 ;pl1 : f1 channel - power level for pulse (default) ;pl2 : f2 channel - power level for pulse (default) ;p1 : f1 channel - 90 degree high power pulse ;p2 : f1 channel - 180 degree high power pulse ;p3 : f2 channel - 90 degree high power pulse ;p12: 40ms using gaussian shape ;p16: homospoil/gradient pulse ;d1 : relaxation delay; 1-5 * T1 ;d2 : 1/(2J)XH ;d12: delay for power switching [20 usec] ;d13: short delay [3 usec] ;d16: delay for homospoil/gradient recovery ;NS: 2 * n ;p14 : 500us at sp3 ;spnam3: Crp60,0.5,20.1 ;sp3: carbon hard power pulse de 25us ;sp7: carbon hard power pulse de 25us ;p24 : 2ms at sp7 ;spnam7: Crp60com.4 ;cnst2: = J(XH) for transfer1 ;cnst3: = J(XH) for transfer2 ;for z-only gradients: ;gpz1: 20% ;gpz2: -20% ;gpz3: 20% ;gpz4: -20% ;gpz5: 50% ;gpz6: 13% ;use gradient files: ;gpnam1: SINE.100 ;gpnam2: SINE.100 ;gpnam3: SINE.100 ;gpnam4: SINE.100 ;gpnam5: SINE.100 ;gpnam6: SINE.100