;1dghsqc ;Double_selective_1DHSQC ;Selincor variant with selective proton and carbon pulses ;avance-version ;1D-HSQC ;1D H-1/X correlation via double inept transfer ;using gradient pulses for selection ;Juan F. Espinosa, Paloma Vidal, Teodor Parella and Sergi Gil: ;Magnetic Resonance in Chemistry, 49, 507-507 (2011). ;DOI:10.1002/mrc.2782 #include #include #include "p2=p1*2" "p4=p3*2" "d4=1s/(cnst2*4)" "d20=d4-p16-d16" 1 ze 2 d1 do:f2 3 (p1 ph1) d4 pl2:f2 (center (p13:sp3 ph1) (p4 ph2):f2 ) d4 UNBLKGRAD (p1 ph4) (p3 ph3):f2 50u p16:gp1 d16 pl0:f2 (p12:sp2 ph2):f2 50u p16:gp2 d16 pl2:f2 (ralign (p1 ph1) (p3 ph5):f2 ) d4 (center (p13:sp3 ph1) (p4 ph2):f2 ) d20 p16:gp3 d16 (p3 ph6):f2 4u BLKGRAD 4u pl12:f2 go=2 ph31 cpd2:f2 wr #0 d1 do:f2 exit ph1=0 ph2=0 ph3=0 2 ph4=1 ph5=0 ph6=0 ph31=0 2 ;pl1 : f1 channel - power level for pulse (default) ;pl2 : f2 channel - power level for pulse (default) ;pl3 : f1 channel - power level for spin-lock pulse ;p1 : f1 channel - 90 degree high power pulse ;p2 : f1 channel - 180 degree high power pulse ;p3 : f2 channel - 90 degree high power pulse ;p4 : f2 channel - 180 degree high power pulse ;p11 : f1 channel - spin-lock pulse ;p12 : f2 channel - 180 shaped pulse ;p13 : f1 channel - 180 shaped pulse ;p16: homospoil/gradient pulse ;d1 : relaxation delay; 1-5 * T1 ;d4 : 1/(4J)XH ;d16: delay for homospoil/gradient recovery ;cnst2: = J(XH) ;NS: 1 * n ;DS: 16 ;use gradient ratio: gp 1 : gp 2 : gp 3 ; 40 : -40 : 20.1 for C-13 ; 40 : -40 : 8.1 for N-15 ;for z-only gradients: ;gpz1: 40% ;gpz2: -40% ;gpz3: 20.1% for C-13, 8.1% for N-15 ;use gradient files: ;gpnam1: SINE.100 ;gpnam2: SINE.100 ;gpnam3: SINE.100